Water Quality: Arsenic

This month we are going to focus on a water quality standard that is not something we measure when testing water quality in the Chesapeake Bay, but rather in drinking water. This month’s water quality focus is arsenic because it happens to be a naturally occurring compound that is found at relatively high abundance in groundwater, including some of the aquifers here on Maryland’s Eastern Shore. Arsenic is colorless and tasteless and regular consumption of this compound, even at low concentrations, has been linked to cancer and other health problems.

2023 test results from St. Michaels Annual Water Quality Report, published April 2024 [2]

For those of us who live on the Eastern Shore, arsenic is a major concern in our drinking water. In fact, in 2023, the Town of St. Michaels was notified by the EPA that they were in violation of arsenic standards for domestic drinking water, with arsenic levels of 0.017 mg/L (17 ug/L), which is above the allowed Maximum Contaminant Level (MCL) of 0.01 mg/L (10 ug/L) [1]. Because of this violation, the previous arsenic filtering media was removed and replaced, which reduced the arsenic levels below the MCL. 

This is why regular testing of drinking water, both municipal and private wells, is recommended. The Maryland Department of the Environment recommends home wells be tested by a state certified lab every year, with more frequent testing recommended in certain situations, including if there is a pregnant or nursing person living in the home. The Town of St. Michaels is currently testing arsenic levels quarterly, with reported arsenic levels for 2023 ranging between 0.000 to 0.0097 mg/L, with an average level of 0.008 mg/L (8 ug/L) [2].

There is some evidence to suggest that the MCL should be lowered but the EPA and World Health Organization continue to use 0.01 mg/L (10 ug/L) as the maximum allowable amount of arsenic [3]. This has less to do with the known exposure levels at which negative health impacts occur but rather the technological limit of measuring and purification technology. In fact, the EPA has a non-enforceable Maximum Contaminant Level Goal of 0 ug/L and they proposed a MCL of 5 ug/L (0.005 mg/L) for a national standard but this was never adopted [3].

Because arsenic is a naturally occurring element, it is also found in the waters of the Chesapeake Bay. The concentrations of this compound have less to do with human activity and more to do with river flow (which is connected to how much groundwater is entering the system) and with biological processes that cycle arsenic through different forms. During hypoxic periods (recall from last month that this means low oxygen levels in the water), inorganic forms of arsenic are released from sediments at the bottom of the Bay, while phytoplankton produce organic forms of arsenic when phosphorus is a limiting nutrient [4]. And while some arsenic is naturally occurring, some does come from humans in the form of urban runoff but also through the use of arsenic based wood treatments like Chromated Copper Arsenate, which is commonly used for pilings and bulkheads. However, arsenic is not generally considered a problem contaminant in the Chesapeake Bay, except from certain types of pollution such as coal ash [5]. This means that there is no specific target for arsenic levels in the Chesapeake Bay and researchers do not sample for it as part of routine environmental water quality analysis.

Testing for arsenic involves bringing a sample back to the lab for analysis; unlike some of the other water quality parameters that we’ve discussed this year, there is no in-situ test for arsenic, which means you can’t just stick a YSI sonde in the water and get a reading. Samples are often processed to remove everything but the arsenic and then the amount of arsenic is determined through HPLC (high performance liquid chromatography), spectrophotometry, or mass-spectrometry, all of which require expensive laboratory equipment to perform.

While arsenic is naturally occurring in groundwater, lower levels of water in aquifers can lead to higher concentrations of arsenic. While drought is less of an issue in Maryland, our changing climate is leading to increased arsenic concentrations in some areas such as the Western US [6]. Here in Maryland, overuse of aquifers may also drop water levels, leading to increases in arsenic levels. We like to think that water is an abundant resource, and it is in some regions, but on a long enough timeline it is a finite resource and we should work to preserve and extend the use of this resource as best we can.

Ultimately, the best thing you can do to keep yourself safe is to test your water regularly. If you are concerned about arsenic levels in your drinking water, whole house water system filters are available that can remove substantial amounts of arsenic but you’ll need to do some research on which ones are proven to remove arsenic.

 

References:

[1] https://www.stmichaelsmd.gov/media/21

[2] https://www.stmichaelsmd.gov/media/26

[3] https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8985943/

[4] https://wwwbrr.cr.usgs.gov/projects/GWC_chemtherm/FinalAbsPDF/riedel.pdf

[5] https://phys.org/news/2023-12-cancer-causing-metals-chesapeake-bay-tributary.html

[6] https://phys.org/news/2023-05-arsenic.html

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